01Steed,
are the 5.4 3V blocks also aluminum? If so what is needed to mate my 2V heads to them?
Nope, they're iron, with exception to the Ford GT block which is cost prohibitive for 99.99% of us.
Your 2V heads will bolt right up to any 3V V8 modular block. The block doesn't have any characteristics that make it a 3V or 2V (except maybe that front left coolant passage like the 4V's).