I'd suspect you are going to spend alot.
Figure a valve job to be $225 for the set of heads, and that's without repairing any damage.
Then you have the new valve itself, possibly an entire set and the repair work.
Keep in mind too, you don't just take one head to a head shop (i mean you can, but it's not wise to only take one). You take them both, so you can't split the cost in half by only taking one there.
Unless this is a set of high end race heads, i'd say repairing any significant damage won't be cost effective.