Head Bolts

It depends on what kind of "gasket sealer" you're talking about; there are many different kinds. Silicone can work, but it is not entirely reliable in my experience.

I have ARP bolts and used their Teflon sealer. It's like a grainy white plumber's dope and I think it may affect fastener torque readings less than other sealers.
 
I stopped using the teflin based liquid sealers a few years back, I use black permatex on the lower bolts....make sure you clean the threads are clean.

Moly on the uppers