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AC refrigerant question.

  • Thread starter Thread starter Edster
  • Start date Start date Apr 22, 2008
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Edster

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Aug 13, 2000
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League City, Texas
Apr 22, 2008
#1
  • Apr 22, 2008
  • #1
Has anyone attempted to use R-134a in an R-12 system and if so what are/were the results?
 

rbohm

Founding Member
Apr 12, 2002
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tucson,az
Apr 22, 2008
#2
  • Apr 22, 2008
  • #2
if you do it right, there is no problem, but you may be disappointed with the end result depending on how efficient your condenser is. the conversion is fairly easy overall, you have to replace the receiver/dryer, and flush the system thoroughly to eliminate all traces of the oil used in the R12 system. it would be best to also replace the condenser with a more efficient one, replace the compressor with one that is also more efficient such as the sanden 508, and replace the stock hoses with later barrier style hoses. the R134a molecule is smaller than the R12 molecule. the first thing you need to do is take the car to a certified a/c specialist and have them recover the remaining R12, and flush the system. after you have made the needed changes, take the car back and have them draw down the system so that you can add the new refrigerant, or have them do it. DO NOT add refrigerant until the sight glass is clear with the R134a as you WILL run into compressor lock. you need to have a set of R134a gauges if you add the refrigerant yourself.
 

Edster

Founding Member
Aug 13, 2000
500
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League City, Texas
Apr 23, 2008
#3
  • Apr 23, 2008
  • #3
The condenser, dryer, the sight glass hose/s are new(stock size) they have just been in my garage for about ten years. The evaporator assembly is stock 1966. They system was working 'til my Dad took it apart(long story involving overheating issues which are now fixed). He had put a really large condenser from an old station wagon w/ a 390. The unit would get so cold it would spit ice at you. But I don't think this will e the case w/ R-134a or even w/ R-12 because of the size of the "stock" condenser. BTW I live in Texas so it gets HOT and the car is black on black! Go figure huh!?
 
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01ragtop

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May 20, 2004
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Apr 23, 2008
#4
  • Apr 23, 2008
  • #4
R134a in a R-12 system is a no-no. R-134a uses a polyester oil, while R-12 uses a mineral oil. If you mix R-134a with mineral oil it will foam your oil and wipe your AC compressor bearings pretty quick. There are some kits that supposedly neutralize the effect. I haven't tried one in a long time, but they used to be junk.
 
5

5.0ina66

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Apr 23, 2008
#5
  • Apr 23, 2008
  • #5
01ragtop said:
R134a in a R-12 system is a no-no. R-134a uses a polyester oil, while R-12 uses a mineral oil. If you mix R-134a with mineral oil it will foam your oil and wipe your AC compressor bearings pretty quick. There are some kits that supposedly neutralize the effect. I haven't tried one in a long time, but they used to be junk.
Click to expand...

Yep, I agree. With that in mind, I'd go to an AC shop or a good auto parts store and get a couple quarts of AC flush and flush the AC system until you can't flush it no mo' Then replace the dryer, inspect all the lines, replace and lube all the o-rings, button it up, put a vacuum on it, and charge 'er up with 134a. You could always replace the lines and/or do a sanden compressor swap too. Really old R12 rated lines can disinegrate when exposed to R134a.
 
N

noblesteed

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Sep 10, 2007
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Apr 23, 2008
#6
  • Apr 23, 2008
  • #6
Hey 5.0ina66...... have you considered using duracool refrigerant? check them out at www.duracool.com just a thought...hope it helps
 
5

5.0ina66

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Jun 6, 2003
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Apr 23, 2008
#7
  • Apr 23, 2008
  • #7
noblesteed said:
Hey 5.0ina66...... have you considered using duracool refrigerant? check them out at www.duracool.com just a thought...hope it helps
Click to expand...
yeah, I use enviro-safe...tree hugger friendly, cheap, easier on the system, cools like R12, and doesn't respond to moisture. As far as I'm concerned, R134 can go f**k itself As long as you don't get one of the cheapo 'replacement' freons with propane or any other stoopid chemicals in it, that's what I'd do if it were mine.
 

Edster

Founding Member
Aug 13, 2000
500
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League City, Texas
Apr 23, 2008
#8
  • Apr 23, 2008
  • #8
Looks like I'm going to have to find me a place that has duracool. I checked out the website and I was pretty much sold. It is a hydrocarbon coolant which leads me to believe it must be similar to the propane that is/was used in the portable refrigerators found in RV/motor homes.
 

valley82

Member
May 16, 2005
204
2
19
San Diega, Ca.
Apr 23, 2008
#9
  • Apr 23, 2008
  • #9
www.icorinternational.com HOTSHOT-been using it as a replacment for R-12 and 134A for years...
 

Edster

Founding Member
Aug 13, 2000
500
1
19
League City, Texas
Apr 24, 2008
#10
  • Apr 24, 2008
  • #10
It sure seems like we have had a suitable replacement for quite some time. Sounds like corruption, corporation, and big gov't. Anyway looks like I am going to go for one of the two (icor or duracool) I just have to find a place that uses it.
Thanks for the info.
 
G

grainboy

Member
Feb 2, 2006
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Apr 25, 2008
#11
  • Apr 25, 2008
  • #11
r12 alternative

I have used freeze12 and HP38 and have lost compressors in 1 week. I see freon on craigslist every day for $20 per can. I have six in my garage waiting for me to install the "driver Kit" on my 66.
 

valley82

Member
May 16, 2005
204
2
19
San Diega, Ca.
Apr 26, 2008
#12
  • Apr 26, 2008
  • #12
There is pretty-much only two ways to trash a compressor that fast.
1. Incorrect refrigerant charge...TOO MUCH=liquid returning to the compressor breaking valves/pistons, etc.
TOO LITTLE=compressor will not be cooled by the returning gas can smoke the bearings.
2. mismatched system components.

The thing to be careful of is that different refrigerants require different amounts to be "properly charged".

The best way to charge a system regardless of refrigerant that is used is by measuring superheat and subcooling.

But I can tell you that R414 "HOT SHOT" is by far a better refrigerant than 134a, and is a little beter than R12 at moving heat.
 
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01ragtop

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May 20, 2004
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Apr 26, 2008
#13
  • Apr 26, 2008
  • #13
valley82 said:
There is pretty-much only two ways to trash a compressor that fast.
1. Incorrect refrigerant charge...TOO MUCH=liquid returning to the compressor breaking valves/pistons, etc.
TOO LITTLE=compressor will not be cooled by the returning gas can smoke the bearings.
2. mismatched system components.

The thing to be careful of is that different refrigerants require different amounts to be "properly charged".

The best way to charge a system regardless of refrigerant that is used is by measuring superheat and subcooling.

But I can tell you that R414 "HOT SHOT" is by far a better refrigerant than 134a, and is a little beter than R12 at moving heat.
Click to expand...

Even a improper charge shouldn't trash a compressor that fast. Too little charge should be safeguarded against by the use of a low pressure cutoff, and I have seen compressors overcharged to the point they freeze over solid and still not have any internal damage. ( not saying its okay to overcharge, because I have also seen pistons split in two because of an overfeeding fault)

Using the wrong oil/refrigerant combo will eat a compressor quick.


EDIT: I should point out that the broken piston I mentioned earlier was not in an automotive application.
 

valley82

Member
May 16, 2005
204
2
19
San Diega, Ca.
Apr 26, 2008
#14
  • Apr 26, 2008
  • #14
I was responding to the post refering to freeze12 smoking a compressor.
134a is the only refrigerant for car ac that will cause you a problem with the wrong oil.
You can use POE or standard oil in R-12,FR12,Hotshot charged systems with out problems.
So that being said, if you trash a compressor and you are not using 134a then you either overcharged or undercharged the system...that assumes that the system was properly evacuated and the system operates normally(all components function corectly).
Overcharging a system (low superheat) will cause liquid refrigerant to mix with the oil washing the bearings causing bearing failure if you way overcharge a system you could cause the compressor to try to compress liquid(refrigerant/oil) resulting in failure.
If ya don't believe me go buy a can of 134a (12oz.) and add it to a new cars ac system then see how long the compressor lasts.
 
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01ragtop

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May 20, 2004
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Apr 26, 2008
#15
  • Apr 26, 2008
  • #15
valley82 said:
I was responding to the post refering to freeze12 smoking a compressor.
134a is the only refrigerant for car ac that will cause you a problem with the wrong oil.
You can use POE or standard oil in R-12,FR12,Hotshot charged systems with out problems.
So that being said, if you trash a compressor and you are not using 134a then you either overcharged or undercharged the system...that assumes that the system was properly evacuated and the system operates normally(all components function corectly).
Overcharging a system (low superheat) will cause liquid refrigerant to mix with the oil washing the bearings causing bearing failure if you way overcharge a system you could cause the compressor to try to compress liquid(refrigerant/oil) resulting in failure.
If ya don't believe me go buy a can of 134a (12oz.) and add it to a new cars ac system then see how long the compressor lasts.
Click to expand...


I understand what you meant, but if the system is working properly a short charge won't hurt the compressor because it has a low pressure "safety" cut-out. An overcharge will take down a compressor given time, but I have seen them freeze up with no internal damage. I also mentioned that I have seen some bad things happen when overfeeding/overcharge is not rectified. SO, on the overcharge we are in agreement. As for refrigerant/oil combos take a look at this. The first row of samples show what some of this "drop in" stuff will do to mineral oil. Now you know why the Freeze 12 took out the compressor so fast.

Bottom line is this: There is no true drop in replacement for R-12. Even the r414b (hotshot) runs with a short charge. That is not to say it won't work, but if you have ever seen a system with a liquid line sight glass and R-414b it will have bubbles, and that means refrigerant is flashing before the metering device. In a low temp application this is more prevalent, and usually the solution is to adjust the TXV, or change the metering device if it is not adjustable. ICOR international will tell you just to charge the system to 80 percent, but IMHO that is marketing hype. It would be hard to sell their refrigerant as a "drop in" replacement for r-12 if they had to have an asterisk explaining that little fact.

Bottom line: if your looking for a cheap replacement for r-12, Hotshot will work in a car AC. Just keep in mind the link above.

More to the topic, however, is the evap and condenser in the OP's car. If they have not been sealed from the elements since your dad pulled the AC out, I'm not sure I would use them at all. That's just me though.

EDIT: So no one is mislead: The website that I posted the link to regarding the oil Miscibility is owned by Autofrost or R406a. While the samples are real what they fail to mention on that page is that r406a will eventually break down mineral oil and become very discolored. It is recommended that you use a AB( Alkyl Benzene) refrigerant oil with either r406a or r414b, but now we are right back to square one with the r134a issue. So considering the fact that the oils at least should be changed, R134a is the better choice because it is not a blend of refrigerants like the R12 replacements. The blended replacements can frationalize and the different refrigerants will leak at different rates. In the case of Autofrost(r406a), it can leave you with a flammable substance.

There is a reason EVERY major auto manufacturer uses R134a
 
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01ragtop

Member
May 20, 2004
88
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San Diego
Apr 26, 2008
#16
  • Apr 26, 2008
  • #16
As for Duracool: http://www.epa.gov/Ozone/snap/refrigerants/hc-12a.html

In summary point number 4 from the above link:

May hydrocarbon refrigerants be used to replace CFC-12, commonly referred to as "Freon® ," in cars?

No. It is illegal to use hydrocarbon refrigerants like HC-12a® and DURACOOL 12a® as substitutes for CFC-12 in automobile or truck air conditioning under any circumstances.
 

valley82

Member
May 16, 2005
204
2
19
San Diega, Ca.
Apr 27, 2008
#17
  • Apr 27, 2008
  • #17
Party on wane...use what ever makes you get that warm and fuzzy feeling!!!
But for a novice I would strongly sugest R-12 or Hotshot...and if you're worried about the oil getting "darker" switch it to POE?!?
But the big three auto manufacturers tried just changing the oil to POE and running 134a in R12 systems in the early 90's and if you owned a 90-93ford/chevy/dodge and lived in arizona in the summer you already know that the a/c would not keep up at temps above 100degrees F. reason...R-134a does not tranfer heat as well as R-12 and that is not an opinion that is fact.
 
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01ragtop

Member
May 20, 2004
88
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7
San Diego
Apr 27, 2008
#18
  • Apr 27, 2008
  • #18
valley82 said:
Party on wane...use what ever makes you get that warm and fuzzy feeling!!!
But for a novice I would strongly sugest R-12 or Hotshot...and if you're worried about the oil getting "darker" switch it to POE?!?.
Click to expand...

"darker" due to acidic breakdown of the oil, and if your have to change oil it is not a "drop in" replacement.


valley82 said:
But the big three auto manufacturers tried just changing the oil to POE and running 134a in R12 systems in the early 90's and if you owned a 90-93ford/chevy/dodge and lived in arizona in the summer you already know that the a/c would not keep up at temps above 100degrees F. reason...R-134a does not transfer heat as well as R-12 and that is not an opinion that is fact.
Click to expand...
No doubt about it, in an automotive application r-134a in a R-12 system is not as efficient as the old R-12 was. It transfers heat fine in a system that was designed to use R-134a. The reason it doesn't work as well in a R-12 system is, -as someone already mentioned- physical molecular size of R-134a is bigger than R-12. And the PT relationship is moved up the scale.

There really is no "drop in' replacement for R-12, this has been my point all along. There are some usable alternatives, but each has its own issue that has to be solved. If the compressor is already old or parts are old then just use the Hotshot or autofrost. but if using new parts or installing a system that was designed for R-12, then change the oil and use the correct refrigerant with that oil. If you don't like R134a, fine just make sure you use the right oil for the Hotshot or what ever you use.
 

Rusty67

20+ Year Stangneter
Dec 3, 2002
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Apr 27, 2008
#19
  • Apr 27, 2008
  • #19
After reading this entire post to this point I've learned a lot but I'm still a little confused as to what would be best for me as well as the original poster.

If you AC system is completely evacuated and it was originally designed for r12 and you need new parts in there anyways, whats the best way to go. I guess best would mean gets coldest and gets there quick.

What year did Ford switch to 134a ?
 
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01ragtop

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May 20, 2004
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Apr 27, 2008
#20
  • Apr 27, 2008
  • #20
Rusty67 said:
After reading this entire post to this point I've learned a lot but I'm still a little confused as to what would be best for me as well as the original poster.

If you AC system is completely evacuated and it was originally designed for r12 and you need new parts in there anyways, whats the best way to go. I guess best would mean gets coldest and gets there quick.

What year did Ford switch to 134a ?
Click to expand...


If only there was one answer to this question.

In a system designed for r-12, I you could use AutoFrost. Just make sure you know you have mineral oil and not PAG oil. Autofrost(r406a) contains chlorine that will fail PAG oil. Should be mineral oil if the system was designed for R-12. Make absolutely sure you do not have any leaks with a vacuum (If you want to be even more sure you could use nitrogen @ 150psi, then do a vacuum. You may or may not have access to the equipment to do this). Having no leaks is important because r406a can become flammable if the blend of refrigerants leak off . The refrigerants used to make r406a leak at different rates, and one of them is Isobutane.

Another option, Use R-12. You can buy it on ebay.(the no leak part still applies, but not because of flammability)

For an old system that I thought was going to die soon I would use one of the above options (probably r12), and plan on replacing it with a new R134a system.

Hope this helps

Disclaimer: The end user is responsible for any damages or injury. The end user bears all responsibility for proper recovery/disposal of any R12 refrigerant.

Dan

EDIT I don't know off hand when Ford stopped using R-12. Somewhere between 94-96 if memory serves. Also I am not sure if just anyone can get R406a. I Don't think you can, but it would still be cheaper to have a shop go this route than do the retrofit.
 
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