Im with the others on needing more information, but generally a decrease in pulley size will require a tune. Too many things can change. You may saturate the MAF or your fuel system may not be able to compensate. You may also need to pull some timing.
ive got the 4.6 with a vortech v-1 non intercooled im goin to a 3.12" pulley right now its at 5 lbs lookin for around ten and i need to know if the apex safc 2 is compatible cause i can get one kinda cheap and its getting tuned once i get all the stuff that apex allows u to tune every 200 rpms individually so its really tempting