To add to that, in an unmodified, perfectly running, vehicle....the recommended octane will net you the BEST mileage, period.
People with a perfectly running, unmodified, vehicle that is engineered to run on 87 octane, will typically get worse mileage if you use higher octane, mainly due to the fact that the engines sensors will alter the trims and timing to properly burn the fuel.....causing you to LOSE mileage.
A perfect example is my last DD, a 99 Cougar 2.5, MTX. When I first bought it I played the "more is better game" and ONLY ran it on 93 octane...the few times I filled up with 87 I would get detonation. After deciding to learn about fuels and octane ratings, I kept with 87 octane. After two or three tanks, the detonation went away...and I got BETTER mileage, doing the same exact driving. I went from a consistent 295-300 miles per tank to 305-320.
There are no "mileage adders" in ANY fuel. Different stations (Shell, Mobile, Hess, ect) use different additives, cleaners, ect. But typically speaking, unless you are getting bad gas....there will be no noticeable difference in mileage between stations.