The wire insulation type determines if it's suitable for engine bay temperatures - not the rating of the wire for current. Some of the best wire you can use is SIS wire used in electrical control panel boards - it's high strand count and has the indivdual wires tinned, so it's like a version of marine rated wire which is also very good wire and built in the same fashion.
The only place to get the stuff is an electrical supply house (probably not stocked - comes in single strand rolls) or a marine supply house (probably stocked but you'd have to remove the jacket to get to the individual wire strands).