i find it hard to believe the coolant is "Boiling" from being vaporized. A 50/50 blend of coolant and water in a coolant system sustaining a 15lb cap will boil around 265 degrees. When you see the coolant boiling, put your finger in it to see if it is hot or not (should be able to tell by vaporization if it is really 265 degrees, this will determing if your coolant is overheated or not)
His problem is there is pressure getting into his coolant system causing "bubbles" which is gas escaping from the system. This gas is most likely combustion fumes leaking through the head gaskets. I've been through 3 blown head gaskets and my last one sounds EXACTLY like yours. Coolant bubbling and coolant smelling like gasoline or "alcohol".
It is well worth the investment to get your heads "milled" to be sure the surface is flat. I think it might cost $40 tops to get this done. If indeed your headgaskets are blown, it is probably because of this or your block deck is not flat either. Chances are your heads are warped and unfortuantly, you gotta spend more $60+ on new gaskets, plus $40 for getting them shaved. Not to mention all the work involved but you do get good at it after a while.
I've been through this 4 times and learned new tricks each time. The good part of all this is you learn from your mistakes!!
Good Luck!!