For every lbs of pressure it raises the boiling point 3*. Your typical cooling system will run about 15 lbs so you have a potential of 45*. If you have a leak you can be loosing a lot of cooling capability. That can be a big portion of your overheating problem. When is it overheating? At a stop or while on the road. Typically if you are overheating at a stop, that also indicates that you don't have enough fan and if you are overheating while moving(say freeway) you don't have enough radiator. When looking for a radiator a common misconception is that more cores is better. What you want to look for in a radiator is how many fins per square inch. What you want is the most surface area. If two radiators being equal thickness say 3 inches, and one is a 4 core and the other is a 2 core each with the same fins per square inch, the 2 core will outcool it. The core will be fatter giving more surface area to cool and the 4 core will have a gap between each row with less surface area. Typically you will only find a fatter core in aluminium radiators because aluminium is stronger than the copper core though copper is better at dissapating heat.
Kevin