POLISHING WHEELS.

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Till it stops cutting into the metal, which will be when it's smooth. Or *at least* until you get the big scratches out. Then move to 320, 400, however high you want to go.

As smooth as they are (no casting to remove = smoother surface to start out with), you shouldn't have to sand much. You could try to just get the large scratches out, then begin to buff.

I redid wheels for a friend with (clearcoated stock polished rims from a Trans Am) black emery compound, tripoli compound, then white rouge compound. They were really tarnished and oxidized.
 
The idea with each successive step of finer paper is to remove the scratches from the previous step. The easiest way is to sand in a perpendicular direction to the previous step. I personally sand stuff as follows:

If it's a rough surface and I need to remove alot of texture, I start with 220, otherwise I start with 320. Then move successively to 400, 600, and 800 grit. After the sanding is done, you need to hit it with tripoli compound, then finally with white rouge compound. Keep buffing with the white rouge until it is mirror-looking enough for your taste. You will need to get some Mother's Mag and Aluminum Polish and hand-polish them with a rag from time to time to maintain the shine in the future.

Edit: I need to give you fair warning....it is NOT a fast process. Plan for it to take longer than you expect. The results will only be as good as the time and care you put into the job.