If your cooling system is functioning as it should (proper pressure, proper mix of antifreeze/water to raise the boiling point) even with aluminum heads there's no reason to worry unless you start to ease up into/above the 220F/230F range. There are MANY aluminum headed and even aluminum blocked oem cars with 195F-ish t'stats whose fans don't even come on until the 210-220 range.
I define overheating as it starts to puke fluid/steam. And of course it's too late then - with aluminum heads you may warp something once it starts to boil. With your set up, if it got to 220-230F or so and appeared to be climbing, I'd start looking for ways to cool it down - turn off the a/c, turn on the heat, pull it over and shut it down and get the hood up. Just as a comparison point, I raced an iron block/aluminum head car in SCCA in the heat of south TX for eight years. Many, many races run in June-August where ambient temps were 100F, track temps were 140-150F. The car would run with the heater on full blast for 30 minutes to 2 hours at a time, between 5000-7000 rpm with the temp gauge sitting right in between 210F-220F, and oil temps - well, who knows what the oil temps were-no gauge. Never had a problem with puking fluid, overheating, etc. On the cool down lap at the end of the race, temps would drop back to 190F or so. The biggest challenge was pitting for fuel (no cooling fan on the car) - no time to cool down before you just stopped the car - it'd often be 230F or so for a minute when I fired it back up and headed back out.