How do I know if it's the Radiator or the Water Pump?

Any water on the ground? Do you mean no water coming out of the actual cap, or going to the resevoir, or what? Check to make sure it's full, not empty. Run it again, and check the fluids. Also, you might want to fill it once it's cool and leave the cap off to see if it bubbles or not. If it bubbles pretty bad and spills out right away, you've got a bad gasket that's eating your water.
 
Turn the car off and reach under the neck of the waterpump. Behind the pulley, on the bottom. There should be a little hole, it's called the weep hole. If that is wet then it's your water pump.

The radiators usually leak from one of the end tanks, so look for that at the bottom corners of the radiator. :nice: